Hydrogen stress cracking occurs when hydrogen penetrates highstrength or hardened metal in a state of tensile stress. Hic test specimens are machined with thickness of 530mm, width 20mm, and length of 100mm is suitable for testing as per the nace standard. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hydrogen induced cracking steel features, applications and. Hic steel hydrogen induced cracking supplier company. Hydrogen induced cracking test for naval steels youtube. Inspection and analysis on samples of hydrogen induced.
Hydrogen induced stress cracking hisc and dnvrpf112 and increase the risk for brittle fracture of the material. Hydrogeninduced cracking hic is still a challenging issue that requires careful assessment and utilization of test validation measures. Ultrasonic detection of hydrogen induced cracking hic in. Alireza bahadori phd, ceng, micheme, cpeng, mieaust, rpeq, in oil and gas pipelines and piping systems, 2017.
In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogen induced cracking hic can occur in metal equipment due to high concentrations of hydrogen. Hydrogen induced cracking test apparatus is rectangular provided with ready to use connections fittings. The hic may promote one mode of fracture in an alloy rather than another form normally observed in benign environments. Sulfide stress cracking mostly occurs in very highly acidic environments.
Exposure of carbon steel equipment to wet h2s service environments can lead to various forms of attack, e. Essentially, the hic test actually tests a sample of steel for its susceptibility to hydrogen embrittlement. Specificationsgrades asmeastm saa 516 grades 606570. Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking. Hydrogen induced cracking test metallurgical services. Test is intended to evaluate resistance to hydrogen induced stepwise cracking only, and not other adverse effects of sour environments such as sulfide stress cracking, pitting, or weight loss from corrosion. In many cases, the testing can take 24 hours or less. There are several types of tests to determine exact type of corrosion resistance property of any material. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Our hydrogen embrittlement testing labs can carry out hisc testing of nickel alloys and duplex stainless steels, widely used in subsea components, to.
Corrosionpedia what is hydrogeninduced cracking hic. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from. Hydrogen induced cracking hic assessment in a gas processing plant case study mohammed a abufour, mohammad. In this issue, the characteristic features and principal causes of hydrogen cracks are described. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Hydrogen induced cracking hic from advanced ndt solutions. Hydrogeninduced cracking an overview sciencedirect topics. The entrapped hydrogen makes cavities in metal that results in cracking due to weak ductility and tensile.
Hydrogen induced stress cracking hisc and dnvrpf112. Hydrogen induced cracking of subsea duplex stainless steel. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Naceastm g193 1 includes the following description of hydrogen blistering. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. Hydrogeninduced cracking also referred to as cold cracking, is caused by the diffusion of hydrogen in the crystal lattice of haz near the fusion boundary atomic hydrogen is dispersed throughout the weld material, making it weak in mechanical properties. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Pdf sulfide stress corrosion cracking and hydrogen. This is a problem commonly found in wet h2ssour service operating environments such as in the oil, gas and petrochemical industry. Stress corrosion cracking and hydrogen embrittlement of high. Largescale wet hydrogen sulfide cracking performance. Stress corrosion cracking and hydrogen embrittlement of.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Cortest offers hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on metal samples in hydrogen enriched aqueous environments such as those in h 2 ssour service applications. Hydrogen induced cracking hic assessment in a gas processing plant. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses. The failure of highstrength fasteners in aerospace equipment as a result of scc or hsc occurs infrequently and almost always unexpectedly. Combatting the problem of hydrogen induced cracking in sour service, hic steel plate is carbon steel plates which are tested to assess the susceptibility of the material to hydrogen induced cracking.
There is a growing acceptance of the term scc to co\er both mechanisms. This type of structural damage typically appears in equipment that undergoes a wet h 2 s service in elevated pressure and temperature profiles. The stripper was made of about 4 inch 10 cm of type 304 stainless steel. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Hydrogen combines with carbon within the alloy and forms methane. Hydrogen blistering has been recognized since the 1940s as a problem in vessel handling sour products. Pdf sulfide stress corrosion cracking and hydrogen induced.
Furthermore, two different types of hydrogen induced damage were evaluated, i. Hydrogen induced cracking results from atomic hydrogen being absorbed by solid metals. Hydrogen embrittlement is a serious problem in certain processing equipment. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. The tests are normally carried out according to nace tm0284. Hydrogen induced cracking test hydrogen induced cracking hic is a mechanical fracture caused by the penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular hydrogen in the internal interface between nonmetallic inclusion and base material. Defects hydrogen cracks in steels identification twi. This atomic hydrogen can form during wet h 2 s corrosion reactions.
Test is intended to evaluate resistance to hydrogeninduced stepwise cracking only, and not other adverse effects of sour environments such as sulfide stress cracking, pitting, or weight loss from corrosion. Hydrogen induced cracking hic is still a challenging issue that requires careful assessment and utilization of test validation measures. Hydrogen induced cracking is associated with absorption of hydrogen and a delayed time to failure incubation time during which hydrogen diffuses into regions of high triaxial stress. We also provide rapid hydrogen embrittlement testing equipment, designed using the patented rising step load rsl technology that you can run inhouse. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. They can develop without warning and lead to dangerous situations if left untreated. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. This can occur during elevatedtemperature thermal treatments and in service during electroplating, contact with maintenance chemicals, wet h 2 s, corrosion reactions, cathodic protection, and operating in highpressure hydrogen containing environments. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Handbook of materials failure analysis with case studies from the oil and gas industry, 2016.
It was not until much later, however, that hic started to be investigated and gained recognition as a potential problem in pipelines as a result of pipeline failures. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydrogen induced cracking steel features, applications. These specimen are machined with thickness of 530 mm, width 20 mm, and length of 100 mm is suitable for testing as per the nace standard. Hydrogen embrittlement failure analysis and consulting. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. To date only duplex stainless steels, together with supermartensitic stainless steels, have been extensively tested. Vargas pm, wastberg s and woollin p, stress based design guidelines for hydrogen induced stress cracking hisc avoidance in duplex materials, proc conf omae 200979504. Hydrogen cracking may also be called cold cracking or delayed cracking. Hic test apparatus is supplied with essential spares for uninterrupted long term testing.
Sulfide stress cracking an overview sciencedirect topics. The susceptibility to hisc has been confirmed in these materials. This type of cracking tends to appear on the surface as small blisters connected by cracks and it can occur when atomic hydrogen enters into the steel. These cracks, if undetected, can lead to failure of the pipeline.
Hydrogen embrittlement consulting us corrosion services. Hydrogen induced cracking tests of high strength steels and. Jet fuel vs diesel vs gasoline how they burn and what color are they. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Astm f519 hydrogen embrittlement he testing element. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. My father, who was also a chemical engineer, showed me the bottom 4 feet approximately, 1. With the development of oil and gas drilling technology, more and more oil pipes and steel materials used for chemical equipment are servicing in the severe conditions like wet hydrogen sulfide electrolyte. Efc publication 17, 2nd edition, corrosion resistant alloys for oil and gas production. Particular attention was given to largescale behavior vs behavior for smallscale laboratory test specimens under an applied tensile stress. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Hydrogen induced cracking of subsea duplex stainless steel twi. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds.
Nace international has adopted the term hydrogeninduced cracking hic. The boltloaded specimen was subjected to both acid and electrochemical cell environments in order to produce hydrogen. Some of the examples are resistance to hydrogen sulphide h2s cracking such as sulphide stress cracking ssc, stress oriented hydrogen induced cracking sohic, hydrogen induced cracking hic, step wise cracking swc, soft zone cracking szc etc. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Test for hydrogen induced cracking in essence, hic testing is actually an evaluation of the steel for susceptibility to hydrogen embrittlement. Hydrogen embrittlement involves the ingress of hydrogen into a component e. May 19, 2009 test for hydrogen induced cracking in essence, hic testing is actually an evaluation of the steel for susceptibility to hydrogen embrittlement. The test procedure involves the evaluation of resistance of pressure vessel steel plate and pipework steels to hydrogen reduced cracking caused by hydrogen absorption from aqueous sulfide corrosion. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. The term environmental stress cracking1 failures is also used sometimes. Hydrogen induced cracking tests of high strength steels. Hic test, hydrogen induced cracking test, step wise cracking.
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